In the whole Franchise (Up to Mahou Tsukai's Cure Magical) There are at least 35+ Pretty Cure's that are either not main cures, or have Cure-like powers:
Regina (Doki Doki)
International Pretty Cure (Happiness Charge)
Cure Tender (Happiness Charge)
Past Princess Pretty Cure (Go! Princess)
Cure Empress, Magician, Priestess (Doki Doki)
Cure Butler (Doki Doki)
Cutie Madame (Doki Doki)
Dark Pretty Cure 5 [Dark Dream, Dark Rouge, Dark Lemonade, Dark Mint, Dark Aqua] (Yes! Pretty Cure 5)
Milky Rose (Yes! Pretty Cure 5 GoGo)
Shiny Luminous (Futari wa Pretty Cure Max Heart)
Bad End Pretty Cure [Bad End Happy, Bad End Sunny, Bad End Peace, Bad End March, Bad End Beauty] (Smile Pretty Cure)
Dark Pretty Cure (HeartCatch)
Mirage Pretty Cure (HeartCatch)
Cure Ange (HeartCatch)
Cure Flower (HeartCatch
Kiryuu Kaoru and Michiru [Cure Windy and Cure Bright] (Futari wa Pretty Cure Splash Star)
Cure Echo (Pretty Cure All Stars) [Sakagami Ayumi]
Miracle Peace (Smile Pretty Cure)
Royal Candy (Smile Pretty Cure)
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