Captain America: Civil War (2016)
Superheroes / actors time spent on the set:
Captain America (Chris Evans) 36 minutes
Tony Stark, aka Iron Man (Robert Downey Jr.) 34 minutes
Winter Soldier (Sebastian Stan) 21 minutes
Black Widow (Scarlett Johansson) less than 12 minutes
Falcon (Anthony Mackie) 10:30 minutes
Black Panther (Chadwick Boseman) 10:15 minutes
Scarlet Witch (Elizabeth Olsen) 10 minutes
Zemo(Daniel Brühl) 9:45 minutes
Spider-Man (Tom Holland) 8:30 minutes
Vision (Paul Bettany) 7 minutes
War Machine (Don Cheadle) 6:00 minutes
Hawkey (Jeremy Renner) 4:45 minutes
Ant-Man (Paul Rudd) 4:45 minutes.