also Fate/Zero
Aquarius: Kiritsugu Emiya
Pisces: Irisviel von Einzbern
Aries: Arturia Pendragon (Saber) (King Arthur)
Taurus: Ryuunosuke Uryuu
Gemini: Hassan-i-sabbah
Cancer: Alexander the Great(Grape) (Rider)
Leo: Gilgamesh (Archer)
Virgo: Diarmuid Ua Duibhne (Lancer)
Libra: Kirei Kotomine
Scorpio: Gilles de Rais (Castor) (Bluebeard)
Sagittarius: Sir Lancelot du lac (Beserker)
Capricorn: Waver Velvet