Loosely based on The Falcon and The Winter Soldier but thier is not actually spoilers and it is NOT going to follow the plot of the tv series. You also do not need to watch it to understand what is happening.
None of the Avengers know Spider-Man's identity, but Peter is an avenger. HOWEVER, he was not in Civil War and therefore has never met Bucky or Sam. For the purpose of this story, he doesn't have a strong connection with any of the Avengers including Tony because none of them know who he is.
May, Ned, and MJ do not know who he is either, but he is still in high school and a big nerd.
I hope you enjoy the story!
-EB